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in stable equilibrium, however, because the slightest jar will abruptly reduce the pressure to the correct vapor pressure. Similarly, if a liquid is expanded beyond the point 0 I, it will sometimes follow the dotted curve shown, but this too would not be a situation of stable equilibrium. These phenomena are respectively known as supersaturation and supercooling. They owe their existence to surface effects, which we have previously ignored. We give a qualitative discussion of the surface effects responsible for supersaturation. Vapor pressure as we have defined it is the pressure at which a gas can coexist in equilibrium with an infinitely large body of its own liquid. We now denote it by Poo(T). On the other hand, the pressure at which a gas can coexist in equilibrium with a finite droplet (of radius r) of its own liquid is not the vapor pressure Poo(T) but a higher pressure Pr(T). The difference between Poo(T) and P/T) is due to the surface tension of the droplet. Before we try to give a qualitative description of the mechanism of condensation, we calculate Pr(T). Suppose a droplet of liquid is placed in an external medium that exerts a pressure P on the droplet. Then the work done by the droplet on expansion is empirically given by dW= PdV- ada (2.15) where da is the increase in the surface area of the droplet and a the coefficient of surface tension. The first law now takes the form

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(2.16)

To import a list of contacts from another program, first export the contacts from that program to a file. Click the File tab, click Open and click Import to open the Import and Export Wizard, which steps you through the import process.

(2.17)

where U oo is the internal energy per unit volume of an infinite droplet. Correspondingly the Gibbs potential takes the form

Consider a droplet of radius r in equilibrium with a gas of temperature T and pressure P. For given T and P, r must be such that the total Gibbs potential of the entire system is at a minimum. This condition determines a relation between P and r for a given T. Let the mass of the droplet be M 1 and the mass

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of the gas be M 2 The total Gibbs potential is of the form 2 Glolal = M 2g 2 + M i g 1 + 4'1Tar (2.18) where g2 and gl are respectively the chemical potential of an infinite body of gas and liquid. We now imagine the radius of the drop changed slightly by evaporation, so that 8Ml = -8M2 . The equilibrium condition is

= 0 = 8M1 (

+ g1 + 8'1Tar 8: )

If you decide to edit a study set later, you can do so from within the technical studies editor. Just click on the name of the study set in the My Study Sets tab, and the de nition of that set will appear on the right side (Figure 6.20) for you to examine or modify. After you have created your study set, you can apply it by choosing it from the Studies menu or by double-clicking it from the My Studies module (Figure 6.21). Generally speaking, the more you use ProphetCharts, the more customized it becomes, and the study sets are one important aspect of this customization.

(2.19)

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(2.20) where p is the mass density of the droplet, we have 2a g2 - g1 = P;

(2.21)

One way to send an e-mail to a contact is to right-click the contact, click Create and then click E-mail. Outlook opens a Message window with the contact s e-mail address in the To field; add a subject, type your message text and click Send.

as the condition for equilibrium. Differentiating both sides with respect to the pressure P of the gas at constant temperature, and remembering the Maxwell relation (8g18Ph = lip, we obtain 1 1 p' -

(2.22)

where p' is the mass density of the gas. We assume that the gas is sufficiently dilute to be considered as ideal gas. Hence (2.23) where m is the mass of a gas atom. Further, lip may be neglected compared to lip', and (8pI8P)::=: O. Therefore

(2.24)

Integrating both sides of this equation we find P as a function of r for a given temperature:

FIGURE 6.21 Whatever study sets you have created in the technical studies editor will also show up alphabetically in the My Study Sets module.

Pr(T) = Poo(T)exp ( pkT-;

20m 1 )

(2.25)

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